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Diss Factsheets
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EC number: 203-445-0 | CAS number: 106-94-5
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
· General information
Personal protection for the First Aider.
Remove contaminated clothing.
If unconscious, place in recovery position and seek medical advice.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least
48 hours after the accident.
· After inhalation
Take affected persons into the open air and position comfortably
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
With symptoms:
Seek medical treatment.
· After skin contact
Remove contaminated clothing.
Immediately wash with water and rinse thoroughly.
Or better;
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
After wide skin contact seek medical treatment.
· After eye contact
Use eye protection.
Rinse opened eye for several minutes under running water. Then consult Oculist.
· After swallowing
Rinse out mouth and then drink (two glasses at the most) water.
Do not induce vomiting.
Call a doctor immediately.
Turn a vomiting person on the side if lying on the back.
If vomiting occurs, the head should be kept low.
· Information for doctor
For detailed information see:
http://gestis-en.itrust.de/
· Most important symptoms and effects, both acute and delayed
Irritations after contact with eyes, skin and mucous membrane.
After inhalation of gas, vapour or aerosol:
Irritating to respiratory tract.
Coughing
Breathing difficulty (dyspnea)
After swallowing:
Irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal tract.
Gastric or intestinal trouble
Systemic effects:
Headache
Somnolence.
Dazed
Ataxia (impaired locomotor coordination)
Nausea
Vomiting
Dizziness
Narcosis
Possible other symptoms are currently not known.
· Danger
Irritation on eyes, skin and respiratory tract.
Degreasing effect on skin.
May be fatal if swallowed and enters airways. Danger of pulmonary oedema.
Danger of impaired breathing.
Danger of disturbed CNS.
Narcotic effect.
Cardiovascular disorders.
May cause liver and kidney damage.
There are at present no indications to further acute dangers for the health.
Further health dangers cannot be excluded however.
· Indication of any immediate medical attention and special treatment needed
Elemental assistance.
Decontamination.
Treat symptomatically and supportively
Fire-fighting measures
Suitable extinguishing agents
CO2, extinguishing powder or water fog. Fight larger
For safety reasons unsuitable extinguishing agen
Special hazards arising from the substance or mi
Formation of toxic and corrosive gases during heating
Can be released in case of fire:
Carbon monoxide and carbon dioxide.
Hydrogen bromide (HBr)
Advice for firefighters
Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
Additional information
Collect contaminated fire fighting water separately. It
Cool endangered containers with water spray jet.
Damp down gases/fumes/haze with water spray jet.
Heating causes a rise in pressure, risk of bursting.
Container explosion may occur under fire conditions.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Put on breathing apparatus
Wear protective equipment. Keep unprotected persons away.
Keep away from sources of ignition.
Ensure adequate ventilation
Bring persons out of danger.
· Environmental precautions:
Do not allow to enter sewing systems, water bodies, groundwater or soil.
Inform respective authorities in case large quantities of the product reach water, sewage system or
soil.
· Methods and material for containment and cleaning up:
Ensure adequate ventilation.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders).
Keep ignition sources away.
Clean up affected area.
May be recycled or disposed of in appropiate containers
Handling and storage
· Handling
· Precautions for safe handling
Keep containers tightly closed.
Prevent formation of aerosols.
Ensure good ventilation/exhaustion at the workplace.
Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).
· Hygiene measures:
Keep away from foodstuffs, beverages and feedinggstuff.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes and skin.
Do not eat, drink or smoke while working.
Store protective clothing separately.
Clean skin thoroughly immediately after handling the product.
· Information about protection against explosions and fires:
Substance/product is flammable.
Fumes can combine with air to form an explosive mixture.
Fire fighting equipment must be available.
Protect from heat.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Use only in explosion-proof area.
Use explosion-proof apparatus / fittings and spark-proof tools.
Flammable mixtures may be formed in empty containers.
· Conditions for safe storage, including any incompatibilities
· Storage
· Requirements to be met by storerooms and containers:
Store in cool location.
Store in original container if possible.
Unsuitable material: Metallic materials.
Do not use light alloy containers.
Unsuitable material: aluminium and aluminium alloy.
Provide solvent resistant, sealed floor.
Provide floor trough without outlet.
Prevent any penetration into the ground.
Suitable material: Steel or stainless steel.
Unsuitable material: Aluminium.
Unsuitable material: Light metals and their alloys.
· Information about storage in one common storage facility:
Store away from foodstuffs.
Do not store together with materials/products which can form dangerous chemical reactions.
See point 10: stability and reactivity.
· Further information about storage conditions:
Store in cool, dry conditions in well closed containers.
Protect from heat and direct sunlight.
Store container in a well ventilated position.
Protect from the effects of light.
Store in a locked cabinet or with restricted to technical experts or their assistants.
· Recommended storage temperature:≤ 25 °C
· Specific end use(s)No further relevant information available.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
· General protective measures:
The usual precautionary measures should be adhered to in handling the chemicals.
· Breathing equipment:
If used in closed systems or well-ventilated area breathing protection is not necessary.
Use breathing protection in case of insufficient ventilation.
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive
or longer exposure use breathing apparatus that is independent of circulating air.
Filter AX.
Filters may also be used one time.
· Protection of hands:
Chemical-protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Check protective gloves prior to each use for their proper condition.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Preventive skin protection by use of skin-protecting agents is recommended.
· Material of gloves
Full contact:
eg Fluorocarbon rubber (Viton)
Recommended thickness of the material: ≥ 0,7 mm
Splash contact:
eg Nitrile rubber, NBR
Recommended thickness of the material: ≥ 0,4 mm
eg Butyl rubber, BR
Recommended thickness of the material: ≥ 0,7 mm
· Penetration time of glove material
Full contact.
Permeation time: > 480 min (8h) EN 374
Splash contact
Permeation time: max. 30 min.
The exact break trough time has to be found out by the manufacturer of the protective gloves and has
to be observed.
· Not suitable are gloves made of the following materials:
Strong gloves
Leather gloves
eg Natural rubber, NR
eg Chloroprene rubber, CR, PVC gloves
eg Nitrile rubber, NBR
Thickness of the material: < 0,4 mm
· Eye protection:
Chemical safety goggles.
· Body protection:
Solvent resistent protective clothing.
Antistatic protective clothing.
Flameproof protective clothing.
Apron, Boots, or suitable chemical protection suit.
Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be ascertained with the respective supplier.
Stability and reactivity
· Reactivity
· Chemical stability
· Conditions to be avoided:
No decomposition if used and stored according to specifications.
To avoid thermal decomposition do not overheat.
Flames, sparks, electrostatic charges.
Light-sensitive.
· Possibility of hazardous reactions
Forms explosive gas mixture with air.
Reacts with strong oxidizing agents.
Reacts with strong bases.
Reacts with alkaline metals.
Reacts with alkaline earth metals.
Reacts with various metals.
· Conditions to avoidNo further relevant information available.
· Incompatible materials:
Metal and metal aloys
Light metals.
Aluminium and his alloys.
· Hazardous decomposition products:
Corrosive gases/vapours
Poisonous gases/vapours
Inflammable gases/vapours
Can be released in case of fire:
Carbon monoxide (CO) and carbon dioxide (CO₂)
Hydrogen bromide
Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
· European waste catalogue
A waste code in accordance with the European Waste Catalogue (EWC) may not be assigned to this product since it admits of a classification only when the consumer uses it for some purpose. In agreement with the waste code must be determined regional waste disposal authority or company.
· Uncleaned packagings: Disposal must be made according to official regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.