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Registration Dossier
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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
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EC number: 404-360-3 | CAS number: 119313-12-1 CG 25-369; IRGACURE 369; TK 11-319
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
Eye contact:
Immediately wash eyes with plenty of running water for at least 15 minutes minimum. Remove contact lenses after the initial 1-2 minutes and
continue flushing for several additional minutes. Occasionally lift the upper and lower eyelids. Seek medical advice if irritation develops and persists.
Skin contact:
Wash affected skin area with plenty of water and soap for at least 15 minutes while removing contaminated clothing and shoes. Seek medical advice if irritation develops and persists.
Ingestion:
Seek medical advice if the victim feels unwell. Wash out mouth with plenty of water and give 2-4 cupfuls of water or milk to drink. Never give anythingby mouth to an unconscious person. Do not induce vomiting.
Inhalation:
Remove the victim from exposure into fresh air if adverse effects (e.g. dizziness, drowsiness or respiratory irritation) occur. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen. Seek medical advice if cough or other symptoms appear.
Fire-fighting measures
Suitable extinguishing media:
Water fog or fine spray, dry chemical fire, carbon dioxide extinguishers and foam; alcohol resistant foam (ACT type) are preferred; general purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Unsuitable extinguishing media: Direct water stream.
Exposure hazards (combustion products):
Combustion products may include and are not limited to: Carbon monoxide, carbon dioxide and nitrogen oxides.
Unusual Fire and Explosion Hazards:
Container may rupture from gas generation in a fire situation. Vapours are heavier than air and may travel a long distance and accumulate in low
lying areas.
Special protective equipment for firefighters:
Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance.
Special methods/instructions:
Keep people away. Isolate fire and deny unnecessary entry. Stay up wind. Keep out of low areas where gases (fumes) can accumulate. Water may not
be effective in extinguishing fire. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all
personnel from the area in case of rising sound from venting safety device or discoloration of the container. Do not use direct water stream. May
spread fire. Eliminate ignition sources. Move container from fire area if this is possible without hazard.
Accidental release measures
Personal precautions:
Wear appropriate personal protective equipment during cleaning. Avoid contact with eyes and skin. Avoid inhalation of dust. Avoid
dust formation. Keep away sources of ignition.
Environmental precautions:
Prevent the material from entering surface water or sanitary sewer system. Do not discharge directly to a water source. If accidental spillage or
washings enter drains or watercourses contact local Environment Agency.
Methods for cleaning up:
Pick up mechanically. Place in suitable and properly labelled waste containers for later disposal. Prevent entry into sewers and waterways. For large
spills: Contain spilled material if possible.
Handling and storage
Handling:
Personal precautions:
Prevent formation of dust. Wear personal protective equipment. Avoid contact with eyes, skin and clothing. Wash thoroughly after
handling. Avoid breathing dust. Dust can form an explosive mixture with air. Take pre-cautionary measure against static charge. Keep away from
sources of heat and ignition.
Technical measures/ Precautions:
Provide good ventilation (local exhaust) of the working area, safety showers and eye wash station near the workplace. Avoid release to the
environment.
Storage:
Technical measures/ Storage conditions:
Keep in the original container. Keep container tightly closed in a cool, dry, well-ventilated place. Keep product away from heat, sparks, flame and
other sources of ignition and out of direct sunlight and away from incompatible materials.
Incompatible products:
Strong oxidizing agents, alkaline and aqueous acids.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- Environmental Hazardous Substance, Solid, N.O.S.
- Chemical name:
- 2-benzyl-2-dimethylamino-4'-morpholinobutyrophenone
- Language:
- English
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 3077
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- Environmental Hazardous Substance, Solid, N.O.S.
- Chemical name:
- 2-benzyl-2-dimethylamino-4'-morpholinobutyrophenone
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- Environmental Hazardous Substance, Solid, N.O.S.
- Chemical name:
- 2-benzyl-2-dimethylamino-4'-morpholinobutyrophenone
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure controls:
Technical measures:
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Organisational measures:
Only personnel who have received appropriate training and are authorized are allowed to handle the substance.
Personal protective equipment:
Respiratory protection:
Use a properly fitted, air-purifying or air-fed respirator complying with NIOSH-approved respirator with minimum APF 10. For emergency conditions
use an approved positive-pressure self-contained breathing apparatus.
Recommended: Dust mask type N95.
Hand protection:
After contamination with product change the gloves immediately and dispose them off according to relevant national and local regulations.
Recommended: Chemical resistant protective gloves (EN 374), Protective index 6, corresponding > 480 minutes of permeation time according to
EN 374.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166).
Skin and body protection:
Wear chemical-resistant protective clothing.
Hygiene measures:
Keep away from foodstuffs, drinks and tobacco. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking
and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Environmental exposure controls:
Procedural and/or control technologies are used to minimize emissions and the resulting exposure during cleaning and maintenance procedures.
Transfer waste gases to a combustion unit or to a powder separator.
Do not apply industrial sludge to natural soils. Sealing of all relevant soil surfaces in the facility.
Stability and reactivity
Chemical Stability: Stable under normal conditions and recommended use.
Conditions to be avoided: Static discharges. Keep product away from heat, sparks, flame and other sources of ignition. Avoid direct sunlight and UV
light.
Materials to avoid: Strong oxidizing agents, alkaline and strong acids.
Hazardous polymerization: Will not occur.
Hazardous decomposition products: Thermal decomposition and burning may produce carbon monoxide, nitrogen oxides and other toxic gases
and vapors.
Disposal considerations
Waste from residues:
Any disposal practices must be in compliance with all national and provincial laws and any municipal or local by-laws governing hazardous waste.
For used, contaminated and residual materials additional evaluations may be required. Do not dump into any sewers, on the ground, or into any body
of water.
Container:
Containers should be cleaned by appropriate method and then re-used or disposed by landfill or incineration as appropriate, in accordance with
local and national regulations. Do not remove label until container is thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.