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EC number: 443-510-2 | CAS number: 738587-10-5
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
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Boiling point
Administrative data
- Endpoint:
- boiling point
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- Study initiation 30th October 2002, experimental phase 6-18th November
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: Meets the criteria for classification as Reliable without restriction according to Klimisch et al (1997)
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 003
- Report date:
- 2003
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.2 (Boiling Temperature)
- GLP compliance:
- yes
- Type of method:
- differential scanning calorimetry
Test material
- Reference substance name:
- -
- EC Number:
- 443-510-2
- EC Name:
- -
- Cas Number:
- 738587-10-5
- Molecular formula:
- C26H14N10Ni2O18S4 as free acid
- IUPAC Name:
- dinickel(2+) sodium 3-carboxy-5-[(1E)-2-(7-oxido-2,6-disulfonaphthalen-1-yl)diazen-1-yl]-1H-1,2,4-triazol-1-ide 3-carboxy-5-[(1E)-2-(7-oxido-2-sulfo-6-sulfonatonaphthalen-1-yl)diazen-1-yl]-1H-1,2,4-triazol-1-ide
Constituent 1
Results and discussion
Boiling point
- Boiling pt.:
- > 420 °C
- Atm. press.:
- 101.3 kPa
Any other information on results incl. tables
Two samples of approximately 10 - 11 mg of test material, sealed in aluminium crucibles with a micro pin hole in the lid, were heated at 10 K.min-1 in a Mettler DSC821e from 25 - 450°C under a nitrogen purge (75 ml.min-1).
In both scans, a broad endothermic peak was observed at a peak temperature of ca. 135°C, followed by a large and vigorous exotherm at a peak temperature of ca. 420°C. It is known from information provided by the Sponsor that the endothermic peak is not associated with melting, as the test substance has been shown not to melt below 310°C. The exothermic peak
suggests that decomposition has occurred, which was confirmed by examination of the samples after cooling, revealing the presence of a residue of 61 - 62% of the original mass. No endothermic peak indicative of boiling was observed.
Applicant's summary and conclusion
- Conclusions:
- The test substance decomposes without boiling.
- Executive summary:
Introduction
The boiling point was measured by DSC, which is an approved method for Test A2.
The heat flow to the sample is measured as it is heated at a constant rate in a sealed crucible which, for a boiling point determination, must have a very small pin hole in the lid. As the boiling point is approached, the heat flow begins to increase as the sample evaporates through the pin hole. Once the sample boils, its temperature remains constant and the furnace temperature moves ahead of that of the sample at a constant rate, causing the heat flow profile to have a linear portion before it again subsides once the sample has boiled away. The temperature at the linear portion of the DSC thermogram is the boiling point.
Results and conclusion
Two samples of approximately 10 - 11 mg of test material, sealed in aluminium crucibles with a micro pin hole in the lid, were heated at 10 K.min-1 in a Mettler DSC821e from 25 - 450°C under a nitrogenpurge (75 ml.min-1).
In both scans, a broad endothermic peak was observed at a peak temperature of ca. 135°C, followed by a large and vigorous exotherm at a peak temperature of ca. 420°C. It is known from information provided by the Sponsor that the endothermic peak is not associated with melting, as the test substance has been shown not to melt below 310°C. The exothermic peak
suggests that decomposition has occurred, which was confirmed by examination of the samples after cooling, revealing the presence of a residue of 61 - 62% of the original mass. No endothermic peak indicative of boiling was observed.
A typical Thermogram is shown in figure 1 and can be found in the 'Attached bckground material' under 'DSC Thermograph from Physical and Chemical properties Report HT02 -405B'
The test substance decomposes without boiling.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
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